Electivire appears in Super Smash Bros. Brawl on the Pokémon Stadium 2 stage as a stage Pokémon. It appears on the Electric stage transformation along with Magnezone, another evolution of a Generation I Pokémon introduced in Diamond and Pearl.
A Thunderbolt Pokémon that attacks by pressing its two tails against a foe and delivering a shock of over 20,000 volts. When hit with an Electric-type attack, it takes no damage, and its Speed increases. Electabuzz evolves into Electivire if you trade it while it's holding an Electirizer. Electivire is famed for having the strongest physical attacks of Electric-type Pokémon.
- Acquiring the Electivire Trophy reveals Pokémon Battle Revolution in the Chronicle. This is a reference to the free Electivire players can receive as a gift from that game via a distribution code, and then transfer it to Diamond or Pearl.